改性氧化石墨烯对废水中重金属的吸附

doi:10.11894/1005-829x.2017.37(5).015

工业水处理 ›› 2017, Vol. 37 ›› Issue (5): 15-19. doi: 10.11894/1005-829x.2017.37(5).015

改性氧化石墨烯对废水中重金属的吸附

李仕友¹, 熊凡¹, 欧阳成炜¹, 谢水波^1,2, 唐振平¹

1. 南华大学污染控制与资源化技术湖南省重点实验室, 湖南衡阳 421001;
2. 南华大学铀矿冶生物技术国防重点学科实验室, 湖南衡阳 421001

收稿日期:2016-03-04 修回日期:2016-03-04 出版日期:2017-05-20 发布日期:2017-06-03
通讯作者: 唐振平,博士,教授。E-mail:zptang01@126.com。 E-mail:zptang01@126.com
作者简介:李仕友(1973-),硕士,副教授。E-mail:lsy730723@163.com。
基金资助:
国家自然科学基金（11475080）；湖南省自然科学基金（2016JJ6125）

Adsorption of modified grapheme oxide for the heavy metals in wastewater

Li Shiyou¹, Xiong Fan¹, Ouyang Chengwei¹, Xie Shuibo^1,2, Tang Zhenping¹

1. Hunan Provincial Key Laboratory of Pollution Control and Resources Technology, University of South China, Hengyang 421001, China;
2. Key Discipline Laboratory for National Defence for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang 421001, China

Received:2016-03-04 Revised:2016-03-04 Online:2017-05-20 Published:2017-06-03

摘要/Abstract

摘要：

简述了石墨烯的基本结构以及氧化石墨烯在结构上的优越性。概述了氧化石墨烯的主要改性方法。针对不同的影响因素，总结了改性氧化石墨烯对废水中重金属的吸附效果。对去除水体中重金属的反应机理进行了归纳，指出了改性氧化石墨烯目前应用在污水处理中存在的问题及应用前景。

关键词: 改性氧化石墨烯, 重金属, 吸附

Abstract:

The basic structure of graphene oxide and the structural advantages of graphene oxide are described briefly. The main modification methods of graphene oxide are summarized. According to different influential factors,a general overview of the adsorption effect of modified graphene oxide on heavy metals in wastewater is presented. The reaction mechanism on the removal of heavy metals from water bodies is concluded,and the problems existed in the application of modified grapheme oxide to wastewater treatment and its application prospect are pointed out.

Key words: modified graphene oxide, heavy metals, adsorption

中图分类号:

X703

李仕友, 熊凡, 欧阳成炜, 谢水波, 唐振平. 改性氧化石墨烯对废水中重金属的吸附[J]. 工业水处理, 2017, 37(5): 15-19.

Li Shiyou, Xiong Fan, Ouyang Chengwei, Xie Shuibo, Tang Zhenping. Adsorption of modified grapheme oxide for the heavy metals in wastewater[J]. INDUSTRIAL WATER TREATMENT, 2017, 37(5): 15-19.

https://www.iwt.cn/CN/Y2017/V37/I5/15

参考文献

[1] Gadipelli S,Guo Z X.Graphene-based materials:Synthesis and gas sorption,storage and separation[J].Progress in Materials Science,2015,69(69):1-60.
[2] Wang J,Feng K,Chen B,et al.Polymer-modified hydrophilic graphe-ne:A promotor to photocatalytic hydrogen evolution for in situ forma-tion of core@shell cobalt nanocomposites[J].Journal of Photochemi-stry&Photobiology A Chemistry,2016,331:247-254.
[3] 王建龙,徐乐瑾.石墨烯材料去除重金属及放射性核素的研究[J].环境科学学报,2015,35(11):3411-3420.
[4] 邓会,孙鹏展,张迎九,等.石墨烯材料在水处理中的应用:传质机制与吸附特性[J].科学通报,2015,33:3196-3209.
[5] Zhao G,Wen T,Chen C,et al.Synthesis of graphene-based nanoma-terials and their application in energy-related and environmental-rela-ted areas[J].RSC Advances,2012,2(25):9286-9303.
[6] Chen H,Cao Y,Wei E,et al.Facile synthesis of graphene nano zero-valent iron composites and their efficient removal of trichloronitro-omethane from drinking water[J].Chemosphere,2016,146:32-39.
[7] Dreyer D R,Todd A D,Bielawski C W,et al.The chemistry of gra-phene oxide[J].Chemical Society Reviews,2009,43(15):5288-5301.
[8] 毕祺.不同氧化程度与缺陷度氧化石墨烯制备及其吸附Cu²⁺研究[D].广州:华南理工大学,2015.
[9] 张秋平.表面引发开环易位聚合方法在石墨烯表面制备聚合物及其应用研究[D].长春:吉林大学,2015.
[10] 薛晓芹.氧化石墨烯的制备、改性及对水中镉的去除研究[D].杭州:浙江大学,2015.
[11] Kumar A S K,Kakan S S,Rajesh N.A novel amine impregnated gr-aphene oxide adsorbent for the removal of hexavalent chromium[J].Chemical Engineering Journal,2013,230(8):328-337.
[12] Hu X J,Liu Y G,Wang H,et al.Removal of Cu (Ⅱ) ions from aque-ous solution using sulfonated magnetic graphene oxide composite[J].Separation&Purification Technology,2013,108(16):189-195.
[13] Gollavelli G,Chang C C,Ling Y C.Facile synthesis of smart magne-tic graphene for safe drinking water:Heavy metal removal and dis-infection control[J].Acs Sustainable Chem.Eng.,2013,1(5):462-472.
[14] Sun Y,Shao D,Chen C,et al.Highly efficient enrichment of radio-nuclides on graphene oxide-supported polyaniline[J].Environmen-tal Science&Technology,2013,47(17):9904-9910.
[15] Chandra V,Kim K S.Highly selective adsorption of Hg²⁺by a poly-pyrrole-reduced graphene oxide composite[J].Chemical Communi-cations,2011,47(13):3942-3944.
[16] 武文琴.氧化石墨烯及其复合材料对重金属铜的吸附性能研究[D].长沙:湖南大学,2013.
[17] Madadrang C J,Kim H Y,Gao G,et al.Adsorption behavior of EDTA-graphene oxide for Pb (Ⅱ) removal[J].Acs Applied Materials&Interfaces,2012,4(3):1186-1193.
[18] 樊伟,卞战强,田向红,等.巯基硅烷改性氧化石墨对砷的吸附性能[J].环境化学,2013,32(5):810-818.
[19] Luo S,Xu X,Zhou G,et al.Amino siloxane oligomer-linked graphene oxide as an efficient adsorbent for removal of Pb (Ⅱ) from waste-water[J].Journal of Hazardous Materials,2014,274(12):145-155.
[20] Ge H,Ma Z.Microwave preparation of triethylenetetramine modified graphene oxide/chitosan composite for adsorption of Cr (Ⅵ)[J].Carbohydrate Polymers,2015,131:280-287.
[21] Oraon R,Adhikari A D,Tiwari S K,et al.Fabrication of nanoclay based graphene/polypyrrole nanocomposite:An efficient ternary electrode material for high performance supercapacitor[J].Applied Clay Science,2015,118:231-238.
[22] 陈丽东,刘锦欣,黄晔,等.ZnO-石墨烯复合材料光催化降解污染物研究进展[J].工业水处理,2015,35(9):17-20.
[23] Shao L,Wang X,Ren Y,et al.Facile fabrication of magnetic cucur-bit
[6] uril/graphene oxide composite and application for uranium removal[J].Chemical Engineering Journal,2016,286:311-319.
[24] Lee Y C,Yang J W.Self-assembled flower-like TiO₂ on exfoliated graphite oxide for heavy metal removal[J].Journal of Industrial and Engineering Chemistry,2012,18(3):1178-1185.
[25] Wang C,Luo H,Zhang Z,et al.Removal of As (Ⅲ) and As (Ⅴ) from aqueous solutions using nanoscale zero valent iron-reduced graphite oxide modified composites[J].Journal of Hazardous Materials,2014,268(3):124-131.
[26] Wu Y,Luo H,Wang H,et al.Adsorption of hexavalent chromium from aqueous solutions by graphene modified with cetyltrimethy-lammonium bromide[J].Journal of Colloid and Interface Science,2013,394(1):183-191.
[27] Liu X,Li J,Wang X,et al.High performance of phosphate-functio-nalized graphene oxide for the selective adsorption of U (Ⅵ) from acidic solution[J].Journal of Nuclear Materials,2015,466(45):56-64.
[28] 宋文成.X射线光谱学研究水中Co (Ⅱ)、Eu (Ⅲ)、As (Ⅴ)和U (Ⅵ)的富集机理[D].合肥:中国科学技术大学,2015.
[29] 张伟强,马建国,刘淑娟,等.改性石墨烯海绵材料对铀的吸附研究[J].东华理工大学学报:自然科学版,2014,37(2):230-235.
[30] Li Z,Chen F,Yuan L,et al.Uranium (Ⅵ) adsorption on graphene oxide nanosheets from aqueous solutions[J].Chemical Engineering Journal,2012,210(6):539-546.
[31] Li S,Lu X,Xue Y,et al.Fabrication of polypyrrole/graphene oxide composite nanosheets and their applications for Cr (Ⅵ) removal in aqueous solution[J].Plos One,2012,7(8):e43328.
[32] Liu X,Pan L,Zhao Q,et al.UV-assisted photocatalytic synthesis of ZnO-reduced graphene oxide composites with enhanced photocata-lytic activity in reduction of Cr (Ⅵ)[J].Chemical Engineering Jo-urnal,2012,183(4):238-243.
[33] Liu X,Pan L,Lu T,et al.Investigation of photocatalytic activities over ZnO-TiO₂-reduced graphene oxide composites synthesized via microwave-assisted reaction[J].Journal of Colloid and Interface Science,2013,394:441-444.
[34] Kai Z,Dwivedi V,Chi C,et al.Graphene oxide/ferric hydroxide composites for efficient arsenate removal from drinking water[J].Journal of Hazardous Materials,2010,182(1/2/3):162-168.

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