工业水处理 ›› 2008, Vol. 28 ›› Issue (6): 47-50. doi: 10.11894/1005-829x.2008.28(6).47

• 试验研究 • 上一篇    下一篇

用CuO/AC催化氧化降解水中LAS的研究

高建峰, 徐春彦, 白婷婷   

  1. 中北大学理学院化学系, 山西太原 030051
  • 收稿日期:2007-12-12 出版日期:2008-06-20 发布日期:2010-10-01
  • 作者简介:高建峰(1969- ),2004年毕业于南开大学,环境化学博士,副教授。电话:0351-3628189,E-mail:jianfenggao@163.com

Research on the catalytic oxidation degradation of aqueous LAS by using CuO/AC

Gao Jianfeng, Xu Chunyan, Bai Tingting   

  1. Department of Chemistry, School of Science, North University of China, Taiyuan 030051, China
  • Received:2007-12-12 Online:2008-06-20 Published:2010-10-01

摘要:

LAS是一类广泛使用的阴离子表面活性剂,具有一定的毒性,且不易降解。文章以CuO/活性炭(AC)为催化剂,H2O2为氧化剂催化氧化降解LAS。结果表明:在H2O2浓度为4.9mmol/L,温度=70℃,pH在5-6,反应时间为2.5h的条件下,LAS降解率67.7%,COD去除率54.1%。

关键词: 十二烷基苯磺酸钠(LAS), CuO/活性炭, 催化氧化

Abstract:

Linear alkylbenzene sulfonate(LAS)is a kind of widely used anionic surfactant.It is toxic, and difficult to be degraded.CuO/activated carbon is used as surfactant and H2O2 as oxidizing agent for the catalytic oxidation of LAS degradation.The results show that LAS degradation rate could reach 67.7% and the COD removal rate could reach 54.1% under optimum conditions: the concentration of hydrogen peroxide is 4.9 mmol/L, water temperature is 70 ℃, pH is between 5 to 6, and reaction time is 2.5 h.

Key words: linear alkylbenzene sulfonate(LAS), CuO/activated carbon, catalytic oxidation

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