铁络合物催化类Fenton氧化研究进展

doi:10.11894/1005-829x.2011.31(7).1

摘要/Abstract

摘要：

综述了铁络合物催化类Fenton氧化的研究进展。铁络合物与铁相比具有更高的催化活性, 可提高水中有机物的去除效果。均相类Fenton存在后续金属离子的去除问题, 因此铁络合物作为催化剂的多相催化类Fenton氧化具有更好的应用前景。重点介绍了高分子负载铁络合物催化类Fenton氧化降解水中有机物的研究现状及铁络合物催化类Fenton氧化的反应活性物种。

关键词: 铁络合物, 类Fenton, 卟啉, 铁酞菁, 多相类Fenton, 高价态铁

Abstract:

The progress in iron complex catalyzed Fenton-like oxidation is reviewed. Compared with iron, the ironcomplex has a higher catalytic activity to improve the removal rate of organic matter from water. The homogeneousFenton-like catalyzed by iron complex may bring a problem of removing metallic ions in subsequent process, so theheterogeneous Fenton-like catalyzed by iron complex has a better future. The current research situation of theFenton-like catalyzed by iron complex loaded on resin is introduced emphatically and the reactive species in theFenton-like catalyzed by iron complex is discussed.

Key words: iron complex, Fenton-like, porphyrin, iron phthalocyanine, heterogeneous Fenton-like, ferryl

中图分类号:

X703.1

郗丽娟, 曹天静, 李大鹏, 杨榕, 徐淑芬, 廖霞, 张瑛洁. 铁络合物催化类Fenton氧化研究进展[J]. 工业水处理, 2011, 31(7): 1-6.

Xi Lijuan, Cao Tianjing, Li Dapeng, Yang Rong, Xu Shufen, Liao Xia, Zhang Yingjie. Progress in the research on iron complex catalyzed Fenton-like oxidation[J]. INDUSTRIAL WATER TREATMENT, 2011, 31(7): 1-6.

https://www.iwt.cn/CN/Y2011/V31/I7/1

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