工业水处理 ›› 2015, Vol. 35 ›› Issue (6): 10-14. doi: 10.11894/1005-829x.2015.35(6).003

• 专论与综述 • 上一篇    下一篇

有机磷系阻垢缓蚀剂的降解对循环冷却水系统影响的预测

张玉玲, 赵华伟, 胡志光, 杨越   

  1. 华北电力大学环境科学与工程学院, 河北保定 071003
  • 收稿日期:2015-03-29 出版日期:2015-06-20 发布日期:2015-07-16
  • 作者简介:张玉玲(1977-),博士后,副教授。电话:0312-7522742,E-mail:zhangyl_77@yahoo.com.cn.
  • 基金资助:

    国家自然科学基金青年基金项目(51308211);河北省自然科学基金项目(E2012502005);中央高校基础科研业务专项项目(13MS77)

Prediction about the effects of the degradation of scale & corrosion inhibitors of organic phosphorus series on the circulating cooling water system

Zhang Yuling, Zhao Huawei, Hu Zhiguang, Yang Yue   

  1. School of Environmental Science & Engineering, North China Electric Power University, Baoding 071003, China
  • Received:2015-03-29 Online:2015-06-20 Published:2015-07-16

摘要:

循环冷却水系统中有机磷系阻垢缓蚀剂的降解是关系到系统安全运行的重要因素。为保障循环冷却水系统的安全运行, 以广泛应用的有机磷酸、有机磷酸酯和有机磷羧酸为目标, 通过总结现有文献中关于上述药剂在天然水体和污水处理中降解的相关报道, 预测了这些药剂在循环冷却水系统内的降解行为, 分析了可能存在的降解途径和降解产物, 预测了有机磷系阻垢缓蚀剂的降解对循环冷却水系统的影响。

关键词: 有机磷, 循环冷却水系统, 降解途径, 降解产物

Abstract:

The degradation of scale and corrosion inhibitors of organic phosphorus series in circulating cooling water systems is the important factor related to system safe operation. In order to guarantee the safe operation of the systems, taking the widely used organic phosphorus, organo-phosphate, and organo-phosphorus carboxylic acid as the target, by summarizing the relevant reports of present literature on the degradation of the above chemicals in natural water body and wastewater treatment, and the degradation behaviors of the chemicals in circulating cooling water system are predicted. The possibly existed degradation route and degraded products are analyzed. The effects of the degradation of scale and corrosion inhibitors of organic phosphorus series on the circulating cooling water system are also predicted.

Key words: organic phosphorus, circulating cooling water systems, degradation route, degradation products

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