工业水处理 ›› 2020, Vol. 40 ›› Issue (7): 56-60. doi: 10.11894/iwt.2019-0623

• 试验研究 • 上一篇    下一篇

磁性MnFe2O4@Al2O3对废水中铜的吸附行为研究

李静1,2(),何宗文3,鲍东杰1,刘占孟2   

  1. 1. 邢台职业技术学院, 河北邢台 054035
    2. 华东交通大学土木建筑学院, 江西南昌 330013
    3. 丰城市水利局, 江西丰城 331100
  • 收稿日期:2020-04-29 出版日期:2020-07-20 发布日期:2020-07-21
  • 作者简介:李静(1976-), 工学硕士, 副教授, 高工。E-mail:67531577@qq.com
  • 基金资助:
    国家自然科学基金项目(51468016);河北省“三三三”人才培养工程资助经费项目资助;河北省科技支撑计划项目(15273628);河北省高等学校科学研究计划青年基金项目(QN20131178)

Adsorption performance of Cu from wastewater using magnetic MnFe2O4@Al2O3

Jing Li1,2(),Zongwen He3,Dongjie Bao1,Zhanmeng Liu2   

  1. 1. Xingtai Polytechnic College, Xingtai 054035, China
    2. School of Civil Engineering and Architecture, East China Jiaotong University, Nanchang 330013, China
    3. Fengcheng Water Conservancy Bureau, Fengcheng 331100, China
  • Received:2020-04-29 Online:2020-07-20 Published:2020-07-21

摘要:

制备核壳磁性吸附剂MnFe2O4@Al2O3用于含铜废水的吸附实验研究。结果表明,MnFe2O4@Al2O3可有效去除水中的铜离子,在MnFe2O4@Al2O3投加质量浓度2.0 g/L、Cu2+质量浓度20 mg/L、pH为6.0、吸附时间180 min的条件下,Cu2+去除率达97%。MnFe2O4@Al2O3对Cu2+的吸附过程符合伪二级动力学方程,为多层化学吸附。VSM分析表明MnFe2O4@Al2O3具备超顺磁性的优势。

关键词: 重金属, 吸附, 磁性纳米复合材料, MnFe2O4@Al2O3

Abstract:

The core/shell nano-particle adsorbent of MnFe2O4@Al2O3 was prepared and introduced in wastewater containing copper ions adsorption experiment. The experimental results showed that the core/shell nano-particle adsorbent of MnFe2O4@Al2O3 could effectively remove copper ions from wastewater. Under the conditions of 20 mg/L Cu2+ concentration, pH 6.0, 2.0 g/L adsorbent dosage, and 180 min adsorption time, the removal rate of Cu2+ was up to 97%. The dynamic process of Cu2+ adsorption followed the pseudo-secondary order model, which was multi-layer chemical adsorption. VSM analysis showed that the MnFe2O4@Al2O3 had the advantage of superparamagnetism.

Key words: heavy metal, adsorption, magnetic nanocomposite, MnFe2O4@Al2O3

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