工业水处理 ›› 2011, Vol. 31 ›› Issue (2): 89-92. doi: 10.11894/1005-829x.2011.31(2).89

• 经验交流 • 上一篇    

冰晶石生产废液在循环冷却水系统中的应用

周军1, 买文宁2, 叶长明1, 张宏忠1, 陈绍伟3   

  1. 1. 郑州轻工业学院材料与化工学院河南省表界面重点实验室, 河南郑州 450002;
    2. 郑州大学环境与水利学院, 河南郑州 450002;
    3. 同济大学环境科学与工程学院, 上海 200092
  • 修回日期:2010-10-22 出版日期:2011-02-20 发布日期:2011-03-02
  • 通讯作者: 联系人杨军 电话13882273652 E-mail:sohu_cn@163.com
  • 作者简介:毛国群(1970)1992年毕业于西安交通大学,工程师,Email:mao19701@yahoo.com.cn

Application of fluorine-containing wastewater from cryolite production to the circulating cooling water system

Zhou Jun1, Mai Wenning2, Ye Changming1, Zhang Hongzhong1, Chen Shaowei3   

  1. 1. Henan Provincial Key Laboratory of Surface & Interface Science, School of Materials and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, China;
    2. College of Environment & Hydraulics, Zhengzhou University, Zhengzhou 450002, China;
    3. School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China
  • Revised:2010-10-22 Online:2011-02-20 Published:2011-03-02

摘要:

针对修武化肥厂循环水系统因结垢导致传热效果降低的现象,选择先剥离黏泥,再采用废酸性冰母液在线清洗的方案对其进行综合处理,经分析清洗下来的钙垢量折合成CaCO3垢量为4764kg,清洗下来的铁锈垢量折合成Fe2O3垢量为75kg,除垢率达到95%以上,洗净率达到90%以上,符合国家要求。清洗过程中监测到碳钢挂片腐蚀速率为1.4929g/(m2.h),远低于行业标准的6g/(m2.h),确保了装置的安全运行。

关键词: 循环冷却水系统, 化学清洗, 废酸性冰母液

Abstract:

Aiming at the phenomenon that the heat-transfer effect gets lower due to the scaling in the circulating water system in Xiuwu Fertilizer Plant,the sticky sludge must be stripped first,and then,acidic fluoride-containing wastewater from cryolite has been used for on-line cleaning,so as to carry on the integrated treatment process.The results show that the calcium cleaned down can be converted to 4 764 kg of CaCO3 scale and the rust scale cleaned down can be converted to 75 g of Fe2O3 scale.The scale removing rate reaches 95% or over and cleaning rate reaches 90% or over.They meet the requirements of national standard.The corrosion rate of carbon steel hanging plate monitored in the process of cleaning is 1.492 9 g/(m2·h),much lower than the trade standard 6 g/(m2·h).Safe operation has thus been assured.

Key words: circulating cooling water systems, chemical cleaning, acidic fluoride-containing wastewater

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